Hazard statement · Physical hazards
What does H260 mean?
In contact with water releases flammable gases which may ignite spontaneously.
- Hazard class
- Substances and Mixtures which, in contact with water, emit flammable gases, Hazard Category 1 (Water-react. 1)
- Pictogram
GHS02Flame- Signal word
- Danger
Categories and label elements
| CLP abbreviation | Pictogram | Signal word |
|---|---|---|
| Water-react. 1 | Danger |
Related precautionary statements (P codes)
The precautionary statements that CLP Annex IV assigns to this class. Not all of them go on the label: under CLP Article 28(3), no more than six precautionary statements appear on the label unless the nature and severity of the hazard require more; the selection depends on the product and its users.
Prevention
Response
- P370+P378In case of fire: Use… to extinguish.
- P302+P335+P334IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages].
Storage
- P402+P404Store in a dry place. Store in a closed container.
Disposal
- P501Dispose of contents/container to …
Build a label with this class. The free label tool works out the pictogram, the signal word and the P statements for the label from the classes you choose.
Where is H260 written in the SDS?
In the prepared SDS the class "Water-react. 1" is matched with the code in Section 2.1, the text of H260 is written in Section 2.2 next to the pictogram and signal word, and the class of the component shows up in Section 3. Section 16 collects the full text of the H statements cited by code. For H260, it must agree with the physical and chemical properties in Section 9 and, if the product is subject to transport rules, it is read together with the ADR information in Section 14.
How does H260 appear on the label?
When you see H260 on a label it is accompanied by GHS02 (flame), and it is written with the signal word "Danger". In the Chemoris template Section 2.2 carries at most 8 H statements; if the limit is exceeded the least severe ones are dropped and a warning is shown. For the bottom of the label, 7 P statements are candidates for this class in CLP Annex IV; under CLP Article 28 at most 6 of them are selected.
Where does it appear in the safety data sheet?
- Section 2.1: classification; the class abbreviation and H260 are given together.
- Section 2.2: label elements; H260 with its full text, pictogram and signal word.
- Section 3: composition table; in the row of every component that has this class.
- Section 16: the full text of the H statements cited as codes in earlier sections.
Class criteria and thresholds for H260
The values below come from the Chemoris rule file (CLP Annex I). They show the condition under which H260 arises in a mixture. For physical hazards and other classes that depend on test data, the result comes from the mixture's own measurement, not from component percentages.
The class behind H260 depends on the mixture's own test data; the Chemoris rule file does not derive it from component percentages and warns the chemist when a component carries it (≥ 1 %) (CLP Annex I 2.x (for physical hazards 1.1.1.3 / Article 6(5) data requirement); 2.16.3 (metal-corrosive mixture)).
H260 compared with H261 and H252
The table below puts H260 next to its closest neighbouring statements; the values are read from the rule data.
| Hazard statement | H260 | H261 | H252 |
|---|---|---|---|
| Class abbreviation | Water-react. 1 | Water-react. 2 | Self-heat. 2 |
| Pictogram | GHS02 | GHS02 | GHS02 |
| Signal word | Danger | Danger | Warning |
| Precautionary statements assigned | 7 | 7 | 5 |
| Concentration cut-off in a mixture | — | — | — |
H260 and H261 carry the same signal word (Danger). Both are shown with the same pictogram (GHS02). The signal word differs: Danger for H260, Warning for H252. Both are shown with the same pictogram (GHS02).
In which SDS sections does H260 appear?
H260 does not stay only in the label section of an SDS; the class itself and the precautionary statements assigned to it shape the content of other sections too. The counts are calculated from the P statements that Annex IV assigns to this class.
| SDS section | Relation to this code |
|---|---|
| 2.1 Classification | Written with the abbreviation Water-react. 1 and the code H260. |
| 2.2 Label elements | H260 appears with its full text, GHS02 (flame) and “Danger”. |
| 3 Composition | The class and code show in the row of every component that carries this class. |
| 9 Physical and chemical properties | The classification has to agree with properties such as flash and boiling point given here. |
| 4 First aid | Of the 7 assigned P statements, 1 belong to the subject of this section: P302+P335+P334. |
| 5 Firefighting | Of the 7 assigned P statements, 1 belong to the subject of this section: P370+P378. |
| 7 Handling and storage | Of the 7 assigned P statements, 3 belong to the subject of this section: P223, P231+P232, P402+P404. |
| 8 Exposure controls / PPE | Of the 7 assigned P statements, 1 belong to the subject of this section: P280. |
| 13 Disposal | Of the 7 assigned P statements, 1 belong to the subject of this section: P501. |
| 14 Transport | ADR mapping: Class 4.3, packing group I; ADR 2.2.43.1.4. |
| 16 Other information | The full text of the H statements cited by code is collected here. |
Statements that appear on the label together with H260
H260 is never printed alone on a label; it sits next to the pictogram and the signal word. The Chemoris selection method (response, prevention, storage, disposal in that order; core statements first) gives these first 5 candidates for this class:
| Rank | P code | Type | Priority | Text |
|---|---|---|---|---|
| 1 | P370+P378 | response | core | In case of fire: Use… to extinguish. |
| 2 | P302+P335+P334 | response | core | IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages]. |
| 3 | P223 | prevention | core | Do not allow contact with water. |
| 4 | P231+P232 | prevention | core | Handle and store contents under inert gas/…. Protect from moisture. |
| 5 | P280 | prevention | core | Wear protective gloves/protective clothing/eye protection/face protection. |
The GHS02 pictogram and “Danger” are printed together. This ranking applies because a label usually carries at most 6 statements; when a combined statement is selected, its parts are not printed again.
Official EU wording of H260 in other languages
When a product is exported to the EU, the SDS and label are expected in the official language of the Member State where it is placed on the market (REACH Article 31(5)). The table gives the official wording of H260 from the CLP Annex III/IV language versions published in the Official Journal of the European Union. Source: EUR-Lex CELEX 02008R1272-20260701.
| Language | Official wording | Class title | Signal word |
|---|---|---|---|
| German | In Berührung mit Wasser entstehen entzündbare Gase, die sich spontan entzünden können. | Stoffe und Gemische, die in Berührung mit Wasser entzündbare Gase entwickeln, Gefahrenkategorie 1 | Gefahr |
| French | Dégage au contact de l'eau des gaz inflammables qui peuvent s'enflammer spontanément. | Substances et mélanges qui, au contact de l'eau, dégagent des gaz inflammables, catégorie de danger 1 | Danger |
| Spanish | En contacto con el agua desprende gases inflamables que pueden inflamarse espontáneamente. | Sustancias y mezclas que, en contacto con el agua, desprenden gases inflamables; categoría 1 | Peligro |
| Italian | A contatto con l'acqua libera gas infiammabili che possono infiammarsi spontaneamente. | Sostanze e miscele che, a contatto con l'acqua, sviluppano gas infiammabili, categoria di pericolo 1 | Pericolo |
| Polish | W kontakcie z wodą uwalniają łatwopalne gazy, które mogą ulegać samozapaleniu. | Substancje i mieszaniny, które w kontakcie z wodą uwalniają gazy łatwopalne, kategoria zagrożenia 1 | Niebezpieczeństwo |
| Dutch | In contact met water komen ontvlambare gassen vrij die spontaan kunnen ontbranden. | Stoffen en mengsels die in contact met water ontvlambare gassen ontwikkelen, gevarencategorie 1 | Gevaar |
| Portuguese | Em contacto com a água liberta gases que se podem inflamar espontaneamente. | Substâncias e misturas que, em contacto com a água, libertam gases inflamáveis, categoria de perigo 1 | Perigo |
| Romanian | În contact cu apa degajă gaze inflamabile care se pot aprinde spontan. | Substanțe și amestecuri care, în contact cu apa, degajă gaze inflamabile, categoria de pericol 1 | Pericol |
Common mistakes with H260
- Deriving the class from percentages: H260 cannot be calculated from component percentages; the mixture's own test data is required (CLP Annex I 2.x (for physical hazards 1.1.1.3 / Article 6(5) data requirement); 2.16.3 (metal-corrosive mixture)).
- Pouring every P candidate onto the label: there are 7 candidates, but CLP Article 28(3) limits a label to 6 precautionary statements (up to 8 when needed).
- Writing unlimited H statements for a multi-class product: in the Chemoris template, Section 2.2 holds at most 8 H statements.
Next steps
To read a statement like H260 correctly on a label and in an SDS, see the guide How to read H and P codes; to pick the class and prepare the label automatically, use the free label tool.
Related hazard statements
Other H statements in the same hazard family as H260 (Water-react.). The difference between categories mostly comes from the degree of severity.
- H261In contact with water releases flammable gases.
Frequently asked questions
Which pictogram and signal word go with H260 on a label?
For H260 the pictogram is GHS02 (flame); it is written with the signal word "Danger".
How many P statements does H260 need?
CLP Annex IV assigns 7 precautionary statements to the class of H260, but under CLP Article 28(3) a label usually carries at most 6 of them; the selection depends on the product and its user.
In which SDS sections does H260 appear?
H260 appears in Sections 2.1 (classification), 2.2 (label), 3 (composition) and 16, and also in 9, 4, 5, 7, 8, 13 and 14.
What is the difference between H260 and H261?
H260 carries Danger and GHS02; H261 carries Danger and GHS02.
Source: Regulation (EC) No 1272/2008 (CLP) Annexes I and III; Turkish SEA Regulation (Official Gazette 28848). The statement is the official English text of CLP Annex III. Pictogram and signal word: CLP Annex I Table 2.12.2. Updated: 6 November 2026.
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