Hazard statement · Physical hazards

What does H220 mean?

Extremely flammable gas.

Hazard class
Flammable gases, Hazard Category 1A (Flam. Gas 1)
Pictogram
GHS02Flame
Signal word
Danger

Categories and label elements

CLP abbreviationPictogramSignal word
Flam. Gas 1GHS02FlameDanger

Related precautionary statements (P codes)

The precautionary statements that CLP Annex IV assigns to this class. Not all of them go on the label: under CLP Article 28(3), no more than six precautionary statements appear on the label unless the nature and severity of the hazard require more; the selection depends on the product and its users.

Prevention

  • P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Response

  • P377Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
  • P381In case of leakage, eliminate all ignition sources.

Storage

  • P403Store in a well-ventilated place.

Build a label with this class. The free label tool works out the pictogram, the signal word and the P statements for the label from the classes you choose.

Where is H220 written in the SDS?

H220 is tracked in three places of the SDS: the classification line in Section 2.1 ("Flam. Gas 1"), the label elements in Section 2.2 and the component list in Section 3. Section 16 repeats the explanation of the code. In addition, it must agree with the physical and chemical properties in Section 9 and, if the product is subject to transport rules, it is read together with the ADR information in Section 14.

How does H220 appear on the label?

The label elements for H220 are: pictogram GHS02 (flame); it is written with the signal word "Danger". In the Chemoris template Section 2.2 carries at most 8 H statements; if the limit is exceeded the least severe ones are dropped and a warning is shown. For the bottom of the label, 4 P statements are candidates for this class in CLP Annex IV; under CLP Article 28 at most 6 of them are selected.

Where does it appear in the safety data sheet?

  • Section 2.1: classification; the class abbreviation and H220 are given together.
  • Section 2.2: label elements; H220 with its full text, pictogram and signal word.
  • Section 3: composition table; in the row of every component that has this class.
  • Section 16: the full text of the H statements cited as codes in earlier sections.

Class criteria and thresholds for H220

The values below come from the Chemoris rule file (CLP Annex I). They show the condition under which H220 arises in a mixture. For physical hazards and other classes that depend on test data, the result comes from the mixture's own measurement, not from component percentages.

The class behind H220 depends on the mixture's own test data; the Chemoris rule file does not derive it from component percentages and warns the chemist when a component carries it (≥ 1 %) (CLP Annex I 2.x (for physical hazards 1.1.1.3 / Article 6(5) data requirement); 2.16.3 (metal-corrosive mixture)).

H220 compared with H221 and H222

The table below puts H220 next to its closest neighbouring statements; the values are read from the rule data.

Hazard statementH220H221H222
Class abbreviationFlam. Gas 1Flam. Gas 2Aerosol 1
PictogramGHS02noneGHS02
Signal wordDangerWarningDanger
Precautionary statements assigned444
Concentration cut-off in a mixture———

The signal word differs: Danger for H220, Warning for H221. The pictogram differs: GHS02 for H220, none for H221. H220 and H222 carry the same signal word (Danger). Both are shown with the same pictogram (GHS02).

H221 H222

In which SDS sections does H220 appear?

H220 does not stay only in the label section of an SDS; the class itself and the precautionary statements assigned to it shape the content of other sections too. The counts are calculated from the P statements that Annex IV assigns to this class.

SDS sectionRelation to this code
2.1 ClassificationWritten with the abbreviation Flam. Gas 1 and the code H220.
2.2 Label elementsH220 appears with its full text, GHS02 (flame) and “Danger”.
3 CompositionThe class and code show in the row of every component that carries this class.
9 Physical and chemical propertiesThe classification has to agree with properties such as flash and boiling point given here.
5 FirefightingOf the 4 assigned P statements, 2 belong to the subject of this section: P377, P381.
7 Handling and storageOf the 4 assigned P statements, 2 belong to the subject of this section: P210, P403.
16 Other informationThe full text of the H statements cited by code is collected here.

Statements that appear on the label together with H220

H220 is never printed alone on a label; it sits next to the pictogram and the signal word. The Chemoris selection method (response, prevention, storage, disposal in that order; core statements first) gives these first 4 candidates for this class:

RankP codeTypePriorityText
1P377responsecoreLeaking gas fire: Do not extinguish, unless leak can be stopped safely.
2P381responsecoreIn case of leakage, eliminate all ignition sources.
3P210preventioncoreKeep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
4P403storagecoreStore in a well-ventilated place.

The GHS02 pictogram and “Danger” are printed together. This ranking applies because a label usually carries at most 6 statements; when a combined statement is selected, its parts are not printed again.

Official EU wording of H220 in other languages

When a product is exported to the EU, the SDS and label are expected in the official language of the Member State where it is placed on the market (REACH Article 31(5)). The table gives the official wording of H220 from the CLP Annex III/IV language versions published in the Official Journal of the European Union. Source: EUR-Lex CELEX 02008R1272-20260701.

LanguageOfficial wordingClass titleSignal word
GermanExtrem entzündbares Gas.Entzündbare Gase, Gefahrenkategorie 1AGefahr
FrenchGaz extrêmement inflammable.Gaz inflammables, catégorie de danger 1 ADanger
SpanishGas extremadamente inflamable.Gases inflamables, categoría 1APeligro
ItalianGas altamente infiammabile.Gas infiammabili, categoria di pericolo 1 APericolo
PolishSkrajnie łatwopalny gaz.Gazy łatwopalne, kategoria zagrożenia 1ANiebezpieczeństwo
DutchZeer licht ontvlambaar gas.Ontvlambare gassen, gevarencategorie 1AGevaar
PortugueseGás extremamente inflamável.Gases inflamáveis, categoria de perigo 1APerigo
RomanianGaz extrem de inflamabil.Gaze inflamabile, categoria de pericol 1APericol

Common mistakes with H220

  • Deriving the class from percentages: H220 cannot be calculated from component percentages; the mixture's own test data is required (CLP Annex I 2.x (for physical hazards 1.1.1.3 / Article 6(5) data requirement); 2.16.3 (metal-corrosive mixture)).
  • Writing unlimited H statements for a multi-class product: in the Chemoris template, Section 2.2 holds at most 8 H statements.

Next steps

To read a statement like H220 correctly on a label and in an SDS, see the guide How to read H and P codes; to pick the class and prepare the label automatically, use the free label tool.

Other H statements in the same hazard family as H220 (Flam. Gas). The difference between categories mostly comes from the degree of severity.

Frequently asked questions

Which pictogram and signal word go with H220 on a label?

For H220 the pictogram is GHS02 (flame); it is written with the signal word "Danger".

How many P statements does H220 need?

CLP Annex IV assigns 4 precautionary statements to the class of H220, but under CLP Article 28(3) a label usually carries at most 6 of them; the selection depends on the product and its user.

In which SDS sections does H220 appear?

H220 appears in Sections 2.1 (classification), 2.2 (label), 3 (composition) and 16, and also in 9, 5 and 7.

What is the difference between H220 and H221?

H220 carries Danger and GHS02; H221 carries Warning and none.

Source: Regulation (EC) No 1272/2008 (CLP) Annexes I and III; Turkish SEA Regulation (Official Gazette 28848). The statement is the official English text of CLP Annex III. Pictogram and signal word: CLP Annex I Table 2.2.3. Updated: 6 November 2026.