Hazard statement · Physical hazards

What does H224 mean?

Extremely flammable liquid and vapour.

Hazard class
Flammable liquids, Hazard Category 1 (Flam. Liq. 1)
Pictogram
GHS02Flame
Signal word
Danger

Categories and label elements

CLP abbreviationPictogramSignal word
Flam. Liq. 1GHS02FlameDanger

Related precautionary statements (P codes)

The precautionary statements that CLP Annex IV assigns to this class. Not all of them go on the label: under CLP Article 28(3), no more than six precautionary statements appear on the label unless the nature and severity of the hazard require more; the selection depends on the product and its users.

Prevention

  • P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P233Keep container tightly closed.
  • P240Ground and bond container and receiving equipment.
  • P241Use explosion-proof [electrical/ventilating/lighting/…] equipment.
  • P242Use non-sparking tools.
  • P243Take action to prevent static discharges.
  • P280Wear protective gloves/protective clothing/eye protection/face protection.

Response

  • P303+P361+P353IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
  • P370+P378In case of fire: Use… to extinguish.

Storage

  • P403+P235Store in a well-ventilated place. Keep cool.

Disposal

  • P501Dispose of contents/container to …

Build a label with this class. The free label tool works out the pictogram, the signal word and the P statements for the label from the classes you choose.

Where is H224 written in the SDS?

In the prepared SDS the class "Flam. Liq. 1" is matched with the code in Section 2.1, the text of H224 is written in Section 2.2 next to the pictogram and signal word, and the class of the component shows up in Section 3. Section 16 collects the full text of the H statements cited by code. For H224, it must agree with the physical and chemical properties in Section 9 and, if the product is subject to transport rules, it is read together with the ADR information in Section 14.

How does H224 appear on the label?

When you see H224 on a label it is accompanied by GHS02 (flame), and it is written with the signal word "Danger". In the Chemoris template Section 2.2 carries at most 8 H statements; if the limit is exceeded the least severe ones are dropped and a warning is shown. For the bottom of the label, 11 P statements are candidates for this class in CLP Annex IV; under CLP Article 28 at most 6 of them are selected.

Where does it appear in the safety data sheet?

  • Section 2.1: classification; the class abbreviation and H224 are given together.
  • Section 2.2: label elements; H224 with its full text, pictogram and signal word.
  • Section 3: composition table; in the row of every component that has this class.
  • Section 16: the full text of the H statements cited as codes in earlier sections.

Class criteria and thresholds for H224

The values below come from the Chemoris rule file (CLP Annex I). They show the condition under which H224 arises in a mixture. For physical hazards and other classes that depend on test data, the result comes from the mixture's own measurement, not from component percentages.

ClassCriterionLimit / formulaSource
Flam. Liq. 1Flash point and boiling pointflash point < 23 °C ; initial boiling point ≤ 35 °CCLP Annex I Table 2.6.1; 2.6.2

H224 compared with H225 and H226

The table below puts H224 next to its closest neighbouring statements; the values are read from the rule data.

Hazard statementH224H225H226
Class abbreviationFlam. Liq. 1Flam. Liq. 2Flam. Liq. 3
PictogramGHS02GHS02GHS02
Signal wordDangerDangerWarning
Precautionary statements assigned111111
Concentration cut-off in a mixture———

H224 and H225 carry the same signal word (Danger). Both are shown with the same pictogram (GHS02). The signal word differs: Danger for H224, Warning for H226. Both are shown with the same pictogram (GHS02).

H225 H226

In which SDS sections does H224 appear?

H224 does not stay only in the label section of an SDS; the class itself and the precautionary statements assigned to it shape the content of other sections too. The counts are calculated from the P statements that Annex IV assigns to this class.

SDS sectionRelation to this code
2.1 ClassificationWritten with the abbreviation Flam. Liq. 1 and the code H224.
2.2 Label elementsH224 appears with its full text, GHS02 (flame) and “Danger”.
3 CompositionThe class and code show in the row of every component that carries this class.
9 Physical and chemical propertiesThe classification has to agree with properties such as flash and boiling point given here.
4 First aidOf the 11 assigned P statements, 1 belong to the subject of this section: P303+P361+P353.
5 FirefightingOf the 11 assigned P statements, 1 belong to the subject of this section: P370+P378.
7 Handling and storageOf the 11 assigned P statements, 7 belong to the subject of this section: P210, P233, P240.
8 Exposure controls / PPEOf the 11 assigned P statements, 1 belong to the subject of this section: P280.
13 DisposalOf the 11 assigned P statements, 1 belong to the subject of this section: P501.
14 TransportADR mapping: Class 3, packing group I; ADR 2.2.3.1.3.
16 Other informationThe full text of the H statements cited by code is collected here.

Statements that appear on the label together with H224

H224 is never printed alone on a label; it sits next to the pictogram and the signal word. The Chemoris selection method (response, prevention, storage, disposal in that order; core statements first) gives these first 5 candidates for this class:

RankP codeTypePriorityText
1P303+P361+P353responsecoreIF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
2P370+P378responsecoreIn case of fire: Use… to extinguish.
3P210preventioncoreKeep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
4P233preventioncoreKeep container tightly closed.
5P240preventioncoreGround and bond container and receiving equipment.

The GHS02 pictogram and “Danger” are printed together. This ranking applies because a label usually carries at most 6 statements; when a combined statement is selected, its parts are not printed again.

Official EU wording of H224 in other languages

When a product is exported to the EU, the SDS and label are expected in the official language of the Member State where it is placed on the market (REACH Article 31(5)). The table gives the official wording of H224 from the CLP Annex III/IV language versions published in the Official Journal of the European Union. Source: EUR-Lex CELEX 02008R1272-20260701.

LanguageOfficial wordingClass titleSignal word
GermanFlüssigkeit und Dampf extrem entzündbar.Entzündbare Flüssigkeiten, Gefahrenkategorie 1Gefahr
FrenchLiquide et vapeurs extrêmement inflammables.Liquides inflammables, catégorie de danger 1Danger
SpanishLíquido y vapores extremadamente inflamables.Líquidos inflamables, categoría 1Peligro
ItalianLiquido e vapori altamente infiammabili.Liquidi infiammabili, categoria di pericolo 1Pericolo
PolishSkrajnie łatwopalna ciecz i pary.Substancje ciekłe łatwopalne, kategoria zagrożenia 1Niebezpieczeństwo
DutchZeer licht ontvlambare vloeistof en damp.Ontvlambare vloeistoffen, gevarencategorie 1Gevaar
PortugueseLíquido e vapor extremamente inflamáveis.Líquidos inflamáveis, categoria de perigo 1Perigo
RomanianLichid și vapori extrem de inflamabili.Lichide inflamabile, categoria de pericol 1Pericol

Common mistakes with H224

  • Pouring every P candidate onto the label: there are 11 candidates, but CLP Article 28(3) limits a label to 6 precautionary statements (up to 8 when needed).
  • Writing unlimited H statements for a multi-class product: in the Chemoris template, Section 2.2 holds at most 8 H statements.

Next steps

To read a statement like H224 correctly on a label and in an SDS, see the guide How to read H and P codes; to pick the class and prepare the label automatically, use the free label tool.

Other H statements in the same hazard family as H224 (Flam. Liq.). The difference between categories mostly comes from the degree of severity.

  • H225Highly flammable liquid and vapour.
  • H226Flammable liquid and vapour.

Frequently asked questions

Which pictogram and signal word go with H224 on a label?

For H224 the pictogram is GHS02 (flame); it is written with the signal word "Danger".

How many P statements does H224 need?

CLP Annex IV assigns 11 precautionary statements to the class of H224, but under CLP Article 28(3) a label usually carries at most 6 of them; the selection depends on the product and its user.

In which SDS sections does H224 appear?

H224 appears in Sections 2.1 (classification), 2.2 (label), 3 (composition) and 16, and also in 9, 4, 5, 7, 8, 13 and 14.

What is the difference between H224 and H225?

H224 carries Danger and GHS02; H225 carries Danger and GHS02.

Which numerical limits apply to H224 in a mixture?

Flam. Liq. 1: flash point &lt; 23 °C ; initial boiling point ≤ 35 °C.

Source: Regulation (EC) No 1272/2008 (CLP) Annexes I and III; Turkish SEA Regulation (Official Gazette 28848). The statement is the official English text of CLP Annex III. Pictogram and signal word: CLP Annex I Table 2.6.2. Updated: 6 November 2026.