What does P241 mean?

What kind of precautionary statement is P241?

Prevention statements (P2xx) describe the measures that stop exposure or an accident before it happens: staying away from heat and ignition sources, wearing personal protective equipment, not breathing vapour or dust, washing hands after work. They are the rules a user applies before starting to work with the product.

Which hazards is it used for?

In the CLP Annex IV assignment table, P241 is assigned to the classes of these hazard statements:

• H224Extremely flammable liquid and vapour.
• H225Highly flammable liquid and vapour.
• H226Flammable liquid and vapour.
• H228Flammable solid.

How many hazard statements is P241 assigned to?

In the CLP Annex IV assignment table, P241 is provided for the classes of 4 H statements in total: 4 physical hazard statements. The lowest-numbered example is H224 and the highest-numbered is H228. Whether a mixture label carries this statement depends on those classes really applying to the mixture.

Neighbouring statements of the same kind

The statements closest in number to P241 in the prevention group:

• P234Keep only in original packaging.
• P235Keep cool.
• P240Ground and bond container and receiving equipment.
• P242Use non-sparking tools.
• P243Take action to prevent static discharges.
• P244Keep valves and fittings free from oil and grease.

How is P241 read?

The text of P241 is 4 words long. It contains options separated by a slash; the preparer keeps the option that fits the product and deletes the others. The part in square brackets is specific to the product or the manufacturer and is completed with the relevant detail.

Where is P241 written in the SDS?

In the SDS, P241 is written in Section 2.2 (label elements) with its code and the text "Use explosion-proof [electrical/ventilating/lighting/…] equipment.". Being a prevention statement, it sits among the prevention lines. The statement should also agree with the safe handling precautions in Section 7.

How does P241 appear on the label?

On the label P241 appears together with its text; under CLP Article 28(3) a label usually carries at most 6 precautionary statements. In the Chemoris selection method, prevention statements are considered in position 2. If the core statements exceed 6, Article 28(3) allows up to 8; when a combined statement is chosen, its individual parts are not repeated on the label. As P241 is on the list of precautionary statements of Annex IV, it can be used in current labels and SDSs; Chemoris writes it into the document only when the relevant prevention candidate is selected.

Which classes and which priority is P241 assigned to?

In the CLP Annex IV assignment table, P241 appears in 4 class/category entries (1 different H statements). Priority split: secondary (priority 2) in 4 entries. Of these entries, 2 carry the signal word “Danger”, 1 carry “Warning” and 1 need no signal word. The pictograms that most often accompany it: GHS02 (3).

The class families it appears in most often: Flam. Liq. (3) and Flam. Sol. * (1).

Classes that P241 is assigned to

The first 4 rows of 4 entries in the CLP Annex IV assignment table (by priority and hazard order):

Statements assigned together with P241

The precautionary statements that most often appear with P241 in the same class entries (with entry count):

• P370+P378In case of fire: Use… to extinguish. (4)
• P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. (4)
• P240Ground and bond container and receiving equipment. (4)
• P280Wear protective gloves/protective clothing/eye protection/face protection. (4)
• P303+P361+P353IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. (3)

Where does P241 stand in the prevention group?

P241 is number 16 of the 38 statements in the P2xx group. The group holds 2 combined and 4 withdrawn statements and 33 single valid statements. Combined statements merge several situations on one line; withdrawn statements are replaced by their current equivalents.

Which SDS section does P241 feed?

Because of its number and its prevention kind, P241 relates to Section 7 Handling and storage of the SDS; in Section 2.2 it is written with its code and text. Statements in the same number range feed the same section.

Checklist when writing P241

• The text contains options separated by a slash; the preparer keeps only the option that fits the product.
• The part in square brackets is specific to the manufacturer or product and is not left unfilled.
• The text ends with “…”; the supplier supplies the completion.
• P241 should agree with Section 7; in Section 2.2 it is written with its code and text.
• The text is 4 words long; if the label space is narrow, choosing a combined statement can save room.

Official EU wording of P241 in other languages

When a product is exported to the EU, the SDS and label are expected in the official language of the Member State where it is placed on the market (REACH Article 31(5)). The table gives the official wording of P241 from the CLP Annex III/IV language versions published in the Official Journal of the European Union. Source: EUR-Lex CELEX 02008R1272-20260701.

Next steps

To read a statement like P241 correctly on a label and in an SDS, see the guide How to read H and P codes; to pick the class and prepare the label automatically, use the free label tool.

Where does it appear in the safety data sheet?

Precautionary statements are given with their code and full text in Section 2.2 (label elements) of the safety data sheet. Alternatives separated by a slash or in square brackets (e.g. gloves/protective clothing) are narrowed down to suit the product.

Frequently asked questions