Hazard statement · Physical hazards
What does H241 mean?
Heating may cause a fire or explosion.
- Hazard class
- Self-Reactive Substances and Mixtures, Type B; Organic Peroxides, Type B (Self-react. B)
- Pictogram
GHS01Exploding bomb
GHS02Flame- Signal word
- Danger
Categories and label elements
| CLP abbreviation | Pictogram | Signal word |
|---|---|---|
| Self-react. B | Danger |
Related precautionary statements (P codes)
The precautionary statements that CLP Annex IV assigns to this class. Not all of them go on the label: under CLP Article 28(3), no more than six precautionary statements appear on the label unless the nature and severity of the hazard require more; the selection depends on the product and its users.
Prevention
Response
- P370+P378In case of fire: Use… to extinguish.
- P370+P380+P375In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Disposal
- P501Dispose of contents/container to …
Build a label with this class. The free label tool works out the pictogram, the signal word and the P statements for the label from the classes you choose.
Where is H241 written in the SDS?
H241 is tracked in three places of the SDS: the classification line in Section 2.1 ("Self-react. B"), the label elements in Section 2.2 and the component list in Section 3. Section 16 repeats the explanation of the code. In addition, it must agree with the physical and chemical properties in Section 9 and, if the product is subject to transport rules, it is read together with the ADR information in Section 14.
How does H241 appear on the label?
The label elements for H241 are: pictogram GHS01 (exploding bomb) and GHS02 (flame); it is written with the signal word "Danger". In the Chemoris template Section 2.2 carries at most 8 H statements; if the limit is exceeded the least severe ones are dropped and a warning is shown. For the bottom of the label, 10 P statements are candidates for this class in CLP Annex IV; under CLP Article 28 at most 6 of them are selected.
Where does it appear in the safety data sheet?
- Section 2.1: classification; the class abbreviation and H241 are given together.
- Section 2.2: label elements; H241 with its full text, pictogram and signal word.
- Section 3: composition table; in the row of every component that has this class.
- Section 16: the full text of the H statements cited as codes in earlier sections.
Class criteria and thresholds for H241
The values below come from the Chemoris rule file (CLP Annex I). They show the condition under which H241 arises in a mixture. For physical hazards and other classes that depend on test data, the result comes from the mixture's own measurement, not from component percentages.
The class behind H241 depends on the mixture's own test data; the Chemoris rule file does not derive it from component percentages and warns the chemist when a component carries it (≥ 1 %) (CLP Annex I 2.x (for physical hazards 1.1.1.3 / Article 6(5) data requirement); 2.16.3 (metal-corrosive mixture)).
H241 compared with H240 and H242
The table below puts H241 next to its closest neighbouring statements; the values are read from the rule data.
| Hazard statement | H241 | H240 | H242 |
|---|---|---|---|
| Class abbreviation | Self-react. B | Self-react. A | Self-react. CD |
| Pictogram | GHS01, GHS02 | GHS01 | GHS02 |
| Signal word | Danger | Danger | Danger |
| Precautionary statements assigned | 10 | 10 | 10 |
| Concentration cut-off in a mixture | — | — | — |
H241 and H240 carry the same signal word (Danger). The pictogram differs: GHS01, GHS02 for H241, GHS01 for H240. H241 and H242 carry the same signal word (Danger). The pictogram differs: GHS01, GHS02 for H241, GHS02 for H242.
In which SDS sections does H241 appear?
H241 does not stay only in the label section of an SDS; the class itself and the precautionary statements assigned to it shape the content of other sections too. The counts are calculated from the P statements that Annex IV assigns to this class.
| SDS section | Relation to this code |
|---|---|
| 2.1 Classification | Written with the abbreviation Self-react. B and the code H241. |
| 2.2 Label elements | H241 appears with its full text, GHS01 (exploding bomb) and GHS02 (flame) and “Danger”. |
| 3 Composition | The class and code show in the row of every component that carries this class. |
| 9 Physical and chemical properties | The classification has to agree with properties such as flash and boiling point given here. |
| 5 Firefighting | Of the 10 assigned P statements, 2 belong to the subject of this section: P370+P378, P370+P380+P375. |
| 7 Handling and storage | Of the 10 assigned P statements, 6 belong to the subject of this section: P210, P220, P234. |
| 8 Exposure controls / PPE | Of the 10 assigned P statements, 1 belong to the subject of this section: P280. |
| 13 Disposal | Of the 10 assigned P statements, 1 belong to the subject of this section: P501. |
| 16 Other information | The full text of the H statements cited by code is collected here. |
Statements that appear on the label together with H241
H241 is never printed alone on a label; it sits next to the pictogram and the signal word. The Chemoris selection method (response, prevention, storage, disposal in that order; core statements first) gives these first 5 candidates for this class:
| Rank | P code | Type | Priority | Text |
|---|---|---|---|---|
| 1 | P370+P378 | response | core | In case of fire: Use… to extinguish. |
| 2 | P370+P380+P375 | response | core | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
| 3 | P210 | prevention | core | Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. |
| 4 | P220 | prevention | core | Keep away from clothing and other combustible materials. |
| 5 | P234 | prevention | core | Keep only in original packaging. |
The GHS01, GHS02 pictogram and “Danger” are printed together. This ranking applies because a label usually carries at most 6 statements; when a combined statement is selected, its parts are not printed again.
Official EU wording of H241 in other languages
When a product is exported to the EU, the SDS and label are expected in the official language of the Member State where it is placed on the market (REACH Article 31(5)). The table gives the official wording of H241 from the CLP Annex III/IV language versions published in the Official Journal of the European Union. Source: EUR-Lex CELEX 02008R1272-20260701.
| Language | Official wording | Class title | Signal word |
|---|---|---|---|
| German | Erwärmung kann Brand oder Explosion verursachen. | Selbstzersetzliche Stoffe und Gemische, Typ B; Organische Peroxide, Typ B | Gefahr |
| French | Peut s'enflammer ou exploser sous l'effet de la chaleur. | Substances et mélanges autoréactifs, type B; Peroxydes organiques, type B | Danger |
| Spanish | Peligro de incendio o explosión en caso de calentamiento. | Sustancias y mezclas que reaccionan espontáneamente, de tipo B; Peróxidos orgánicos de tipo B | Peligro |
| Italian | Rischio d'incendio o di esplosione per riscaldamento. | Sostanze e miscele autoreattive, tipo B; Perossidi organici, tipo B | Pericolo |
| Polish | Ogrzanie może spowodować pożar lub wybuch. | Substancje i mieszaniny samoreaktywne, typ B; Nadtlenki organiczne, typ B | Niebezpieczeństwo |
| Dutch | Brand- of ontploffingsgevaar bij verwarming. | Zelfontledende stoffen en mengsels, type B; Organische peroxiden, type B | Gevaar |
| Portuguese | Risco de explosão ou de incêndio sob a acção do calor. | Substâncias e misturas auto-reactivas, Tipo B; Peróxidos orgânicos, Tipo B | Perigo |
| Romanian | Pericol de incendiu sau de explozie în caz de încălzire. | Substanțe și amestecuri autoreactive, tipul B; Peroxizi organici, tipul B | Pericol |
Common mistakes with H241
- Deriving the class from percentages: H241 cannot be calculated from component percentages; the mixture's own test data is required (CLP Annex I 2.x (for physical hazards 1.1.1.3 / Article 6(5) data requirement); 2.16.3 (metal-corrosive mixture)).
- Pouring every P candidate onto the label: there are 10 candidates, but CLP Article 28(3) limits a label to 6 precautionary statements (up to 8 when needed).
- Writing unlimited H statements for a multi-class product: in the Chemoris template, Section 2.2 holds at most 8 H statements.
Next steps
To read a statement like H241 correctly on a label and in an SDS, see the guide How to read H and P codes; to pick the class and prepare the label automatically, use the free label tool.
Related hazard statements
Other H statements in the same hazard family as H241 (Self-react.). The difference between categories mostly comes from the degree of severity.
Frequently asked questions
Which pictogram and signal word go with H241 on a label?
For H241 the pictogram is GHS01 (exploding bomb) and GHS02 (flame); it is written with the signal word "Danger".
How many P statements does H241 need?
CLP Annex IV assigns 10 precautionary statements to the class of H241, but under CLP Article 28(3) a label usually carries at most 6 of them; the selection depends on the product and its user.
In which SDS sections does H241 appear?
H241 appears in Sections 2.1 (classification), 2.2 (label), 3 (composition) and 16, and also in 9, 5, 7, 8 and 13.
What is the difference between H241 and H240?
H241 carries Danger and GHS01, GHS02; H240 carries Danger and GHS01.
Source: Regulation (EC) No 1272/2008 (CLP) Annexes I and III; Turkish SEA Regulation (Official Gazette 28848). The statement is the official English text of CLP Annex III. Pictogram and signal word: CLP Annex I Table 2.8.1. Updated: 6 November 2026.
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