Hazard statement · Physical hazards
What does H281 mean?
Contains refrigerated gas; may cause cryogenic burns or injury.
- Hazard class
- Gases under pressure: Refrigerated liquefied gas (Press. Gas)
- Pictogram
GHS04Gas cylinder- Signal word
- Warning
Categories and label elements
| CLP abbreviation | Pictogram | Signal word |
|---|---|---|
| Press. Gas | Warning |
Related precautionary statements (P codes)
The precautionary statements that CLP Annex IV assigns to this class. Not all of them go on the label: under CLP Article 28(3), no more than six precautionary statements appear on the label unless the nature and severity of the hazard require more; the selection depends on the product and its users.
Storage
- P410+P403Protect from sunlight. Store in a well-ventilated place.
Build a label with this class. The free label tool works out the pictogram, the signal word and the P statements for the label from the classes you choose.
Where is H281 written in the SDS?
In the prepared SDS the class "Press. Gas" is matched with the code in Section 2.1, the text of H281 is written in Section 2.2 next to the pictogram and signal word, and the class of the component shows up in Section 3. Section 16 collects the full text of the H statements cited by code. For H281, it must agree with the physical and chemical properties in Section 9 and, if the product is subject to transport rules, it is read together with the ADR information in Section 14.
How does H281 appear on the label?
When you see H281 on a label it is accompanied by GHS04 (gas cylinder), and it is written with the signal word "Warning". In the Chemoris template Section 2.2 carries at most 8 H statements; if the limit is exceeded the least severe ones are dropped and a warning is shown. For the bottom of the label, 1 P statements are candidates for this class in CLP Annex IV; under CLP Article 28 at most 6 of them are selected.
Where does it appear in the safety data sheet?
- Section 2.1: classification; the class abbreviation and H281 are given together.
- Section 2.2: label elements; H281 with its full text, pictogram and signal word.
- Section 3: composition table; in the row of every component that has this class.
- Section 16: the full text of the H statements cited as codes in earlier sections.
Class criteria and thresholds for H281
The values below come from the Chemoris rule file (CLP Annex I). They show the condition under which H281 arises in a mixture. For physical hazards and other classes that depend on test data, the result comes from the mixture's own measurement, not from component percentages.
The class behind H281 depends on the mixture's own test data; the Chemoris rule file does not derive it from component percentages and warns the chemist when a component carries it (≥ 1 %) (CLP Annex I 2.x (for physical hazards 1.1.1.3 / Article 6(5) data requirement); 2.16.3 (metal-corrosive mixture)).
H281 compared with H280 and H272
The table below puts H281 next to its closest neighbouring statements; the values are read from the rule data.
| Hazard statement | H281 | H280 | H272 |
|---|---|---|---|
| Class abbreviation | Press. Gas | Press. Gas | Ox. Liq. 2 / Ox. Sol. 2 |
| Pictogram | GHS04 | GHS04 | GHS03 |
| Signal word | Warning | Warning | Danger |
| Precautionary statements assigned | 1 | 1 | 5 |
| Concentration cut-off in a mixture | — | — | — |
H281 and H280 carry the same signal word (Warning). Both are shown with the same pictogram (GHS04). The signal word differs: Warning for H281, Danger for H272. The pictogram differs: GHS04 for H281, GHS03 for H272.
In which SDS sections does H281 appear?
H281 does not stay only in the label section of an SDS; the class itself and the precautionary statements assigned to it shape the content of other sections too. The counts are calculated from the P statements that Annex IV assigns to this class.
| SDS section | Relation to this code |
|---|---|
| 2.1 Classification | Written with the abbreviation Press. Gas and the code H281. |
| 2.2 Label elements | H281 appears with its full text, GHS04 (gas cylinder) and “Warning”. |
| 3 Composition | The class and code show in the row of every component that carries this class. |
| 9 Physical and chemical properties | The classification has to agree with properties such as flash and boiling point given here. |
| 7 Handling and storage | Of the 1 assigned P statements, 1 belong to the subject of this section: P410+P403. |
| 16 Other information | The full text of the H statements cited by code is collected here. |
Statements that appear on the label together with H281
H281 is never printed alone on a label; it sits next to the pictogram and the signal word. The Chemoris selection method (response, prevention, storage, disposal in that order; core statements first) gives these first 1 candidates for this class:
| Rank | P code | Type | Priority | Text |
|---|---|---|---|---|
| 1 | P410+P403 | storage | core | Protect from sunlight. Store in a well-ventilated place. |
The GHS04 pictogram and “Warning” are printed together. This ranking applies because a label usually carries at most 6 statements; when a combined statement is selected, its parts are not printed again.
Official EU wording of H281 in other languages
When a product is exported to the EU, the SDS and label are expected in the official language of the Member State where it is placed on the market (REACH Article 31(5)). The table gives the official wording of H281 from the CLP Annex III/IV language versions published in the Official Journal of the European Union. Source: EUR-Lex CELEX 02008R1272-20260701.
| Language | Official wording | Class title | Signal word |
|---|---|---|---|
| German | Enthält tiefgekühltes Gas; kann Kälteverbrennungen oder -verletzungen verursachen. | Gase unter Druck: tiefgekühlt verflüssigtes Gas | Achtung |
| French | Contient un gaz réfrigéré; peut causer des brûlures ou blessures cryogéniques. | Gaz sous pression: gaz liquides réfrigérés | Attention |
| Spanish | Contiene gas refrigerado; puede provocar quemaduras o lesiones criogénicas. | Gases a presión: Gas licuado refrigerado | Atención |
| Italian | Contiene gas refrigerato; può provocare ustioni o lesioni criogeniche. | Gas sotto pressione: gas liquefatto refrigerato | Attenzione |
| Polish | Zawiera schłodzony gaz; może spowodować oparzenia kriogeniczne lub obrażenia. | Gazy pod ciśnieniem: Gaz skroplony schłodzony | Uwaga |
| Dutch | Bevat sterk gekoeld gas; kan cryogene brandwonden of letsel veroorzaken. | Gassen onder druk: sterk gekoeld vloeibaar gas | Waarschuwing |
| Portuguese | Contém gás refrigerado; pode provocar queimaduras ou lesões criogénicas. | Gases sob pressão: Gás liquefeito refrigerado | Atenção |
| Romanian | Conține un gaz răcit; poate cauza arsuri sau leziuni criogenice. | Gaze sub presiune: gaz lichefiat răcit | Atenție |
Common mistakes with H281
- Deriving the class from percentages: H281 cannot be calculated from component percentages; the mixture's own test data is required (CLP Annex I 2.x (for physical hazards 1.1.1.3 / Article 6(5) data requirement); 2.16.3 (metal-corrosive mixture)).
- Mixing up signal words: if any class requires “Danger”, only “Danger” is printed and “Warning” drops out (CLP Article 20(3)).
- Writing unlimited H statements for a multi-class product: in the Chemoris template, Section 2.2 holds at most 8 H statements.
Next steps
To read a statement like H281 correctly on a label and in an SDS, see the guide How to read H and P codes; to pick the class and prepare the label automatically, use the free label tool.
Related hazard statements
Other H statements in the same hazard family as H281 (Press.). The difference between categories mostly comes from the degree of severity.
- H280Contains gas under pressure; may explode if heated.
Frequently asked questions
Which pictogram and signal word go with H281 on a label?
For H281 the pictogram is GHS04 (gas cylinder); it is written with the signal word "Warning".
How many P statements does H281 need?
CLP Annex IV assigns 1 precautionary statements to the class of H281, but under CLP Article 28(3) a label usually carries at most 6 of them; the selection depends on the product and its user.
In which SDS sections does H281 appear?
H281 appears in Sections 2.1 (classification), 2.2 (label), 3 (composition) and 16, and also in 9 and 7.
What is the difference between H281 and H280?
H281 carries Warning and GHS04; H280 carries Warning and GHS04.
Source: Regulation (EC) No 1272/2008 (CLP) Annexes I and III; Turkish SEA Regulation (Official Gazette 28848). The statement is the official English text of CLP Annex III. Pictogram and signal word: CLP Annex I Table 2.5.2. Updated: 6 November 2026.
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