What does H302 mean?

Categories and label elements

CLP abbreviation	Pictogram	Signal word
Acute Tox. 4	GHS07Exclamation mark	Warning

Related precautionary statements (P codes)

The precautionary statements that CLP Annex IV assigns to this class. Not all of them go on the label: under CLP Article 28(3), no more than six precautionary statements appear on the label unless the nature and severity of the hazard require more; the selection depends on the product and its users.

When does a mixture need H302?

For a pure substance H302 comes straight from the classification; for a mixture it is derived from component data. The calculation rules applied to this code are:

• A component of this class is taken into account in a mixture only at a concentration of ≥ 1 %. (CLP Annex I Table 1.1)
• The category of the mixture is calculated from the ATE values of the components (route: oral) with the additivity formula 100/ATEmix = Σ(Ci/ATEi).

For a step-by-step worked example see classifying a mixture under CLP.

Where is H302 written in the SDS?

In the prepared SDS the class "Acute Tox. 4" is matched with the code in Section 2.1, the text of H302 is written in Section 2.2 next to the pictogram and signal word, and the class of the component shows up in Section 3. Section 16 collects the full text of the H statements cited by code. For H302, it is justified in Section 11 (toxicological information) under the relevant effect heading.

How does H302 appear on the label?

When you see H302 on a label it is accompanied by GHS07 (exclamation mark), and it is written with the signal word "Warning". In the Chemoris template Section 2.2 carries at most 8 H statements; if the limit is exceeded the least severe ones are dropped and a warning is shown. For the bottom of the label, 5 P statements are candidates for this class in CLP Annex IV; under CLP Article 28 at most 6 of them are selected.

Where does it appear in the safety data sheet?

• Section 2.1: classification; the class abbreviation and H302 are given together.
• Section 2.2: label elements; H302 with its full text, pictogram and signal word.
• Section 3: composition table; in the row of every component that has this class.
• Section 16: the full text of the H statements cited as codes in earlier sections.

Class criteria and thresholds for H302

The values below come from the Chemoris rule file (CLP Annex I). They show the condition under which H302 arises in a mixture. For physical hazards and other classes that depend on test data, the result comes from the mixture's own measurement, not from component percentages.

H302 compared with H301 and H300

The table below puts H302 next to its closest neighbouring statements; the values are read from the rule data.

The signal word differs: Warning for H302, Danger for H301. The pictogram differs: GHS07 for H302, GHS06 for H301. The signal word differs: Warning for H302, Danger for H300. The pictogram differs: GHS07 for H302, GHS06 for H300.

H301 H300

In which SDS sections does H302 appear?

H302 does not stay only in the label section of an SDS; the class itself and the precautionary statements assigned to it shape the content of other sections too. The counts are calculated from the P statements that Annex IV assigns to this class.

Statements that appear on the label together with H302

H302 is never printed alone on a label; it sits next to the pictogram and the signal word. The Chemoris selection method (response, prevention, storage, disposal in that order; core statements first) gives these first 5 candidates for this class:

The GHS07 pictogram and “Warning” are printed together. This ranking applies because a label usually carries at most 6 statements; when a combined statement is selected, its parts are not printed again.

Official EU wording of H302 in other languages

When a product is exported to the EU, the SDS and label are expected in the official language of the Member State where it is placed on the market (REACH Article 31(5)). The table gives the official wording of H302 from the CLP Annex III/IV language versions published in the Official Journal of the European Union. Source: EUR-Lex CELEX 02008R1272-20260701.

Common mistakes with H302

• Printing too many pictograms: If the skull and crossbones (GHS06) applies, the exclamation mark (GHS07) is not used at all (CLP Article 26(1)(b)).
• Mixing up exposure routes: H302 concerns only the oral route; ATE is calculated separately for each route (CLP Annex I 3.1.3.6.1 (formula), Table 3.1.1 (category ranges), Table 3.1.2 (converted ATE)).
• Mixing up signal words: if any class requires “Danger”, only “Danger” is printed and “Warning” drops out (CLP Article 20(3)).

Next steps

To read a statement like H302 correctly on a label and in an SDS, see the guide How to read H and P codes; to pick the class and prepare the label automatically, use the free label tool.

Related hazard statements

Other H statements in the same hazard family as H302 (Acute Tox.). The difference between categories mostly comes from the degree of severity.

• H300Fatal if swallowed.
• H301Toxic if swallowed.
• H310Fatal in contact with skin.
• H311Toxic in contact with skin.
• H312Harmful in contact with skin.
• H330Fatal if inhaled.
• H331Toxic if inhaled.
• H332Harmful if inhaled.

Frequently asked questions