What does H332 mean?

Categories and label elements

CLP abbreviation	Pictogram	Signal word
Acute Tox. 4	GHS07Exclamation mark	Warning

Related precautionary statements (P codes)

The precautionary statements that CLP Annex IV assigns to this class. Not all of them go on the label: under CLP Article 28(3), no more than six precautionary statements appear on the label unless the nature and severity of the hazard require more; the selection depends on the product and its users.

When does a mixture need H332?

For a pure substance H332 comes straight from the classification; for a mixture it is derived from component data. The calculation rules applied to this code are:

• A component of this class is taken into account in a mixture only at a concentration of ≥ 1 %. (CLP Annex I Table 1.1)
• The category of the mixture is calculated from the ATE values of the components (route: inhalation) with the additivity formula 100/ATEmix = Σ(Ci/ATEi).

For a step-by-step worked example see classifying a mixture under CLP.

Where is H332 written in the SDS?

In the prepared SDS the class "Acute Tox. 4" is matched with the code in Section 2.1, the text of H332 is written in Section 2.2 next to the pictogram and signal word, and the class of the component shows up in Section 3. Section 16 collects the full text of the H statements cited by code. For H332, it is justified in Section 11 (toxicological information) under the relevant effect heading.

How does H332 appear on the label?

When you see H332 on a label it is accompanied by GHS07 (exclamation mark), and it is written with the signal word "Warning". In the Chemoris template Section 2.2 carries at most 8 H statements; if the limit is exceeded the least severe ones are dropped and a warning is shown. For the bottom of the label, 4 P statements are candidates for this class in CLP Annex IV; under CLP Article 28 at most 6 of them are selected.

Where does it appear in the safety data sheet?

• Section 2.1: classification; the class abbreviation and H332 are given together.
• Section 2.2: label elements; H332 with its full text, pictogram and signal word.
• Section 3: composition table; in the row of every component that has this class.
• Section 16: the full text of the H statements cited as codes in earlier sections.

Class criteria and thresholds for H332

The values below come from the Chemoris rule file (CLP Annex I). They show the condition under which H332 arises in a mixture. For physical hazards and other classes that depend on test data, the result comes from the mixture's own measurement, not from component percentages.

H332 compared with H331 and H330

The table below puts H332 next to its closest neighbouring statements; the values are read from the rule data.

The signal word differs: Warning for H332, Danger for H331. The pictogram differs: GHS07 for H332, GHS06 for H331. The signal word differs: Warning for H332, Danger for H330. The pictogram differs: GHS07 for H332, GHS06 for H330.

H331 H330

In which SDS sections does H332 appear?

H332 does not stay only in the label section of an SDS; the class itself and the precautionary statements assigned to it shape the content of other sections too. The counts are calculated from the P statements that Annex IV assigns to this class.

Statements that appear on the label together with H332

H332 is never printed alone on a label; it sits next to the pictogram and the signal word. The Chemoris selection method (response, prevention, storage, disposal in that order; core statements first) gives these first 4 candidates for this class:

The GHS07 pictogram and “Warning” are printed together. This ranking applies because a label usually carries at most 6 statements; when a combined statement is selected, its parts are not printed again.

Official EU wording of H332 in other languages

When a product is exported to the EU, the SDS and label are expected in the official language of the Member State where it is placed on the market (REACH Article 31(5)). The table gives the official wording of H332 from the CLP Annex III/IV language versions published in the Official Journal of the European Union. Source: EUR-Lex CELEX 02008R1272-20260701.

Common mistakes with H332

• Printing too many pictograms: If the skull and crossbones (GHS06) applies, the exclamation mark (GHS07) is not used at all (CLP Article 26(1)(b)).
• Mixing up exposure routes: H332 concerns only the inhalation (vapour) route; ATE is calculated separately for each route (CLP Annex I 3.1.3.6.1 (formula), Table 3.1.1 (category ranges), Table 3.1.2 (converted ATE)).
• Mixing up signal words: if any class requires “Danger”, only “Danger” is printed and “Warning” drops out (CLP Article 20(3)).

Next steps

To read a statement like H332 correctly on a label and in an SDS, see the guide How to read H and P codes; to pick the class and prepare the label automatically, use the free label tool.

Related hazard statements

Other H statements in the same hazard family as H332 (Acute Tox.). The difference between categories mostly comes from the degree of severity.

• H300Fatal if swallowed.
• H301Toxic if swallowed.
• H302Harmful if swallowed.
• H310Fatal in contact with skin.
• H311Toxic in contact with skin.
• H312Harmful in contact with skin.
• H330Fatal if inhaled.
• H331Toxic if inhaled.

Frequently asked questions