Hazard statement · Health hazards

What does H314 mean?

Causes severe skin burns and eye damage.

Hazard class
Skin corrosion/irritation, Hazard Category 1, Sub-Categories 1A, 1B, 1C (Skin Corr. 1A / Skin Corr. 1B / Skin Corr. 1C)
Pictogram
GHS05Corrosion
Signal word
Danger

Categories and label elements

CLP abbreviationPictogramSignal word
Skin Corr. 1AGHS05CorrosionDanger
Skin Corr. 1BGHS05CorrosionDanger
Skin Corr. 1CGHS05CorrosionDanger

Related precautionary statements (P codes)

The precautionary statements that CLP Annex IV assigns to this class. Not all of them go on the label: under CLP Article 28(3), no more than six precautionary statements appear on the label unless the nature and severity of the hazard require more; the selection depends on the product and its users.

Prevention

  • P260Do not breathe dust/fume/gas/mist/vapours/spray.
  • P264Wash … thoroughly after handling.
  • P280Wear protective gloves/protective clothing/eye protection/face protection.

Response

  • P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
  • P303+P361+P353IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
  • P363Wash contaminated clothing before reuse.
  • P304+P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P310Immediately call a POISON CENTER/doctor/…
  • P321Specific treatment (see … on this label).
  • P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Storage

  • P405Store locked up.

Disposal

  • P501Dispose of contents/container to …

Build a label with this class. The free label tool works out the pictogram, the signal word and the P statements for the label from the classes you choose.

When does a mixture need H314?

For a pure substance H314 comes straight from the classification; for a mixture it is derived from component data. The calculation rules applied to this code are:

  • Skin Corr. 1A: A component of this class is taken into account in a mixture only at a concentration of ≥ 1 %. (CLP Annex I Table 1.1; 3.2.3.3.1)
  • Skin Corr. 1A: Summation method: the weighted sum of the qualifying components must reach ≥ 5 % for the mixture to be classified Skin Corr. 1A (H314). (CLP Annex I Table 3.2.3)
  • Skin Corr. 1A: If a component has a harmonised specific concentration limit (SCL) and meets it, the mixture takes the corresponding class directly.
  • Skin Corr. 1B: Summation method: the weighted sum of the qualifying components must reach ≥ 5 % for the mixture to be classified Skin Corr. 1B (H314). (CLP Annex I Table 3.2.3)
  • Skin Corr. 1C: Summation method: the weighted sum of the qualifying components must reach ≥ 5 % for the mixture to be classified Skin Corr. 1C (H314). (CLP Annex I Table 3.2.3)

For a step-by-step worked example see classifying a mixture under CLP.

Where is H314 written in the SDS?

In the prepared SDS the class "Skin Corr. 1A / Skin Corr. 1B / Skin Corr. 1C" is matched with the code in Section 2.1, the text of H314 is written in Section 2.2 next to the pictogram and signal word, and the class of the component shows up in Section 3. Section 16 collects the full text of the H statements cited by code. For H314, it appears in Section 11 (toxicological information), under heading 11.1, as a "Classified" line when the class is among the classes of the mixture.

How does H314 appear on the label?

When you see H314 on a label it is accompanied by GHS05 (corrosion), and it is written with the signal word "Danger". In the Chemoris template Section 2.2 carries at most 8 H statements; if the limit is exceeded the least severe ones are dropped and a warning is shown. For the bottom of the label, 12 P statements are candidates for this class in CLP Annex IV; under CLP Article 28 at most 6 of them are selected.

Where does it appear in the safety data sheet?

  • Section 2.1: classification; the class abbreviation and H314 are given together.
  • Section 2.2: label elements; H314 with its full text, pictogram and signal word.
  • Section 3: composition table; in the row of every component that has this class.
  • Section 16: the full text of the H statements cited as codes in earlier sections.

Class criteria and thresholds for H314

The values below come from the Chemoris rule file (CLP Annex I). They show the condition under which H314 arises in a mixture. For physical hazards and other classes that depend on test data, the result comes from the mixture's own measurement, not from component percentages.

ClassCriterionLimit / formulaSource
Skin Corr. 1AMinimum concentration for a component to be considered≥ 1 %CLP Annex I Table 1.1; 3.2.3.3.1
Skin Corr. 1AAdditive formula by which a mixture reaches this classΣ(Skin Corr. 1A) ≥ 5 %CLP Annex I Table 3.2.3
Skin Corr. 1BMinimum concentration for a component to be considered≥ 1 %CLP Annex I Table 1.1; 3.2.3.3.1
Skin Corr. 1BAdditive formula by which a mixture reaches this classΣ(Skin Corr. 1A/1B) ≥ 5 %CLP Annex I Table 3.2.3
Skin Corr. 1CMinimum concentration for a component to be considered≥ 1 %CLP Annex I Table 1.1; 3.2.3.3.1
Skin Corr. 1CAdditive formula by which a mixture reaches this classΣ(Skin Corr. 1A/1B/1C/1) ≥ 5 %CLP Annex I Table 3.2.3

H314 compared with H318 and H315

The table below puts H314 next to its closest neighbouring statements; the values are read from the rule data.

Hazard statementH314H318H315
Class abbreviationSkin Corr. 1A / Skin Corr. 1B / Skin Corr. 1CEye Dam. 1Skin Irrit. 2
PictogramGHS05GHS05GHS07
Signal wordDangerDangerWarning
Precautionary statements assigned1236
Concentration cut-off in a mixture1 %1 %1 %

H314 and H318 carry the same signal word (Danger). Both are shown with the same pictogram (GHS05). They are not printed together: when Skin Corr. 1A/1B/1C/1 applies, Eye Dam. 1 is not repeated (CLP Annex I 3.3.2.1 and ECHA CLP Kriterleri Rehberi 3.3.2 (H314 → H318 etikette tekrarlanmaz)). The signal word differs: Danger for H314, Warning for H315. The pictogram differs: GHS05 for H314, GHS07 for H315. They are not printed together: when Skin Corr. 1A/1B/1C/1 applies, Skin Irrit. 2 + Eye Irrit. 2 is not repeated (CLP Annex I 3.2.3.3.4 / 3.3.3.3.4 (the more severe class takes precedence)).

H318 H315

In which SDS sections does H314 appear?

H314 does not stay only in the label section of an SDS; the class itself and the precautionary statements assigned to it shape the content of other sections too. The counts are calculated from the P statements that Annex IV assigns to this class.

SDS sectionRelation to this code
2.1 ClassificationWritten with the abbreviation Skin Corr. 1A / Skin Corr. 1B / Skin Corr. 1C and the code H314.
2.2 Label elementsH314 appears with its full text, GHS05 (corrosion) and “Danger”.
3 CompositionThe class and code show in the row of every component that carries this class.
11 Toxicological informationThe health effect is justified here under the relevant endpoint heading.
4 First aidOf the 12 assigned P statements, 7 belong to the subject of this section: P301+P330+P331, P303+P361+P353, P363.
7 Handling and storageOf the 12 assigned P statements, 3 belong to the subject of this section: P260, P264, P405.
8 Exposure controls / PPEOf the 12 assigned P statements, 1 belong to the subject of this section: P280.
13 DisposalOf the 12 assigned P statements, 1 belong to the subject of this section: P501.
14 TransportADR mapping: Class 8, packing group I, Class 8, packing group II and Class 8, packing group III; ADR 2.2.8.1.6.2.
16 Other informationThe full text of the H statements cited by code is collected here.

Statements that appear on the label together with H314

H314 is never printed alone on a label; it sits next to the pictogram and the signal word. The Chemoris selection method (response, prevention, storage, disposal in that order; core statements first) gives these first 5 candidates for this class:

(Skin Corr. 1A)

RankP codeTypePriorityText
1P301+P330+P331responsecoreIF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
2P303+P361+P353responsecoreIF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
3P363responsecoreWash contaminated clothing before reuse.
4P304+P340responsecoreIF INHALED: Remove person to fresh air and keep comfortable for breathing.
5P310responsecoreImmediately call a POISON CENTER/doctor/…

The GHS05 pictogram and “Danger” are printed together. This ranking applies because a label usually carries at most 6 statements; when a combined statement is selected, its parts are not printed again.

Official EU wording of H314 in other languages

When a product is exported to the EU, the SDS and label are expected in the official language of the Member State where it is placed on the market (REACH Article 31(5)). The table gives the official wording of H314 from the CLP Annex III/IV language versions published in the Official Journal of the European Union. Source: EUR-Lex CELEX 02008R1272-20260701.

LanguageOfficial wordingClass titleSignal word
GermanVerursacht schwere Verätzungen der Haut und schwere Augenschäden.Ätz-/Reizwirkung auf die Haut, Gefahrenkategorie 1, Unterkategorien 1A, 1B, 1CGefahr
FrenchProvoque de graves brûlures de la peau et de graves lésions des yeux.Corrosif/irritant pour la peau, catégorie de danger 1, sous-catégories 1A, 1B, 1CDanger
SpanishProvoca quemaduras graves en la piel y lesiones oculares graves.Corrosión o irritación cutáneas, categoría de peligro 1, subcategorías 1A, 1B y 1CPeligro
ItalianProvoca gravi ustioni cutanee e gravi lesioni oculari.Corrosione/irritazione cutanea, categoria di pericolo 1, sottocategorie 1A, 1B, 1CPericolo
PolishPowoduje poważne oparzenia skóry oraz uszkodzenia oczu.Działanie żrące/drażniące na skórę, kategoria zagrożenia 1, podkategorie 1A, 1B, 1CNiebezpieczeństwo
DutchVeroorzaakt ernstige brandwonden en oogletsel.Huidcorrosie/-irritatie, gevarencategorie 1 en subcategorieën 1A, 1B, 1CGevaar
PortugueseProvoca queimaduras na pele e lesões oculares graves.Corrosão/irritação cutânea, categoria de perigo 1, subcategorias 1A, 1B, 1CPerigo
RomanianProvoacă arsuri grave ale pielii și lezarea ochilor.Corodarea/iritarea pielii, categoria de pericol 1, subcategoriile 1A, 1B, 1CPericol

Common mistakes with H314

  • Pouring every P candidate onto the label: there are 12 candidates, but CLP Article 28(3) limits a label to 6 precautionary statements (up to 8 when needed).
  • Writing unlimited H statements for a multi-class product: in the Chemoris template, Section 2.2 holds at most 8 H statements.

Next steps

To read a statement like H314 correctly on a label and in an SDS, see the guide How to read H and P codes; to pick the class and prepare the label automatically, use the free label tool.

Other H statements in the same hazard family as H314 (Skin Corr.). The difference between categories mostly comes from the degree of severity.

  • H310Fatal in contact with skin.
  • H311Toxic in contact with skin.
  • H312Harmful in contact with skin.
  • H315Causes skin irritation.
  • H317May cause an allergic skin reaction.
  • H318Causes serious eye damage.
  • H319Causes serious eye irritation.

Frequently asked questions

Which pictogram and signal word go with H314 on a label?

For H314 the pictogram is GHS05 (corrosion); it is written with the signal word "Danger".

How many P statements does H314 need?

CLP Annex IV assigns 12 precautionary statements to the class of H314, but under CLP Article 28(3) a label usually carries at most 6 of them; the selection depends on the product and its user.

When does a mixture need H314?

A component of this class is taken into account in a mixture only at a concentration of ≥ 1 %. Summation method: the weighted sum of the qualifying components must reach ≥ 5 % for the mixture to be classified Skin Corr. 1A (H314). Details are in the section "When does a mixture need H314?" above.

Does H314 cover other statements on the label?

Yes. When H314 applies, the less severe Eye Dam. 1 for the same endpoint is left out of the label because the stronger class already covers it.

In which SDS sections does H314 appear?

H314 appears in Sections 2.1 (classification), 2.2 (label), 3 (composition) and 16, and also in 11, 4, 7, 8, 13 and 14.

What is the difference between H314 and H318?

H314 carries Danger and GHS05; H318 carries Danger and GHS05. They are not printed together: when Skin Corr. 1A/1B/1C/1 applies, Eye Dam. 1 is not repeated (CLP Annex I 3.3.2.1 and ECHA CLP Kriterleri Rehberi 3.3.2 (H314 → H318 etikette tekrarlanmaz)).

Which numerical limits apply to H314 in a mixture?

Skin Corr. 1A: ≥ 1 %; Skin Corr. 1A: Σ(Skin Corr. 1A) ≥ 5 %; Skin Corr. 1B: ≥ 1 %.

Source: Regulation (EC) No 1272/2008 (CLP) Annexes I and III; Turkish SEA Regulation (Official Gazette 28848). The statement is the official English text of CLP Annex III. Pictogram and signal word: CLP Annex I Table 3.2.5. Updated: 6 November 2026.